I don't totally understand what was going on, but my guess is there may have been an earlier incident, a jackknife which damaged the air and electric connection to the second trailer. I don't see any lights on the second trailer, so something more involved happened than the brakes just being locked up.
It does look to me like the cops are just escorting the truck until it can move out of the way, somewhat.
The road surface is slippery, it's not such a big deal to drag the second trailer with the brakes locked up, (which, ideally is the lighter one of the set.....'ideally' π ) The default position of truck brakes on the tractor and trailers is 'set', the air pressure from the truck is what releases them, keeps them open. My guess is the FedWREX truck jacknifed, was blocking busy I-80, and they asked if he could move the truck.
When it's really cold, the brakes on the truck or trailer can freeze closed when you're parked overnight. If it's the trailer brakes, it's not so bad, assuming the pavement is not dry. π You can drag the trailer slowly a bit until the brakes release. If it's the tractor brakes frozen, you're not moving.