Modern batteries for smartphones, cameras, tablets, laptop computers, etc. are a technology called Lithium Polymer batteries (or Lipo for short). Lipos batteries are pretty awesome: They're flat, hold a huge amount of power, they don't self-discharge, and they don't have 'charge memories'. They're also fragile, easy to damage, and
very dangerous when mistreated.
If you like your device (or your car) , it's worth the trip back to your car to remove it on a hot day. Leaving Lipos in a hot car is dangerous.
Period.
- The odds of an explosion is almost zero. (at least an explosion more powerful than a party balloon popping)
- The odds of a chemical leak almost zero.
- The odds of collateral damage (ie. your car, or house) is moderate.
- The odds of your device being destroyed is high.
- Significantly shortening the life of the battery is certain.
If you want to see what happens when Lithium Polymer batteries overheat, Google image search for "Lipo Fire" - you'll probably get lots of pictures of radio-controlled vehicle batteries. Alternatively look at the results from a YouTube - search for "Lipo Fire".
- LiPo batteries blow up like balloons, vent from a corner, and catch fire.
- The smell is horrible, which is good because the smoke is also highly toxic.
A good quote from an Radio Controlled Hobby Forum:
LiPo cells will get damaged by external heat. Most manufacturers recommend keeping the cells under 60 deg C or 176 deg F. In my experience, a cell will start to balloon up and the layers start to delaminate once the temperature rises above 90 deg C (194 deg F). If the temperature is extremely severe – the cell will go into thermal runaway and you will have a flaming mess. The thermal volatility is directly related to the cell chemistry. LiCoO2 is the industry standard and unfortunately, the most volatile. LiFePO4 (used in most power tools) is the least volatile and LiMnO4 Spinel (used by Apogee) is somewhere in between. Many of the responsible LiPo manufacturers are using mixtures and additives to LiCoO2 to decrease volatility at the expense of voltage output. Unfortunately, most manufacturers still use pure LiCoO2 since it seems to make the most power.
The quote talks about battery "balloon up". This is caused by the battery producing Hydrogen. The cell, normally flat and about 2-5mm thick, will puff up to several times its original thickness. The 'bag' the battery is in is pretty tough stuff. This doesn't work out well if the battery is housed in a tight container, such as the inside of the camera, or phone. It'll break the device at a minimum, and runs the risk of the Hydrogen venting and igniting.
90 C is pretty hot, but if your camera is in the sun, and sealed in a hot car, it's not unreasonable to reach 60-70 C. Repeated exposure (ie. every single day in the sun) permanently damages the battery. Charging or discharging the battery also increases its internal temperature.
If you get the internal temperature of the battery above 187 C (which is probably not attainable in a hot car), it'll start a runaway thermal reaction. Like thermite, it can't be put out. Like thermite, it's hot enough to melt metal.
One final note: Radio Controlled vehicles are
extreme examples. Consumer electronics have charge, discharge, and temperature circuitry to 'protect' the battery. Radio Controlled batteries have none of that - it's just the battery.